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2 edition of adsorptive stripping voltammetry on mercury film electrodes found in the catalog.

adsorptive stripping voltammetry on mercury film electrodes

A. Economou

adsorptive stripping voltammetry on mercury film electrodes

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  • 33 Currently reading

Published by UMIST in Manchester .
Written in English


Edition Notes

StatementA. Economou ; supervised by P.R. Fielden.
ContributionsFielden, P.R., DIAS.
ID Numbers
Open LibraryOL20160419M

Determination of heavy metals on macro- and micro-electrodes by adsorptive cathodic stripping voltammetry and anodic stripping voltammetry. Abstract This thesis describes the application of macro, micro, ultra-microelectrodes and microelectrode arrays to the measurement of trace concentrations of nickel and cobalt in sediment and natural.   Mercury film electrodes consist of a thin “film” of mercury deposited on an electrode surface (typically glassy carbon) by reduction of a mercury(II) salt in solution. It can be difficult to obtain a reproducible film, and this can affect the reproducibility of the results, particularly when compared to the reproducibility obtained using a. Stripping voltammetry with collection The determination of mercury Robert English Allen Robert English, "Stripping voltammetry with collection The determination of mercury " ().Retrospective Theses and Dissertations. the determination of metal ions using stripping voltammetry at a thin Au-film electrode. adsorptive stripping square-wave voltammetry. Analytical Letters, 21, Hart J.P., Wring S.A. () Pre-concentration of vitamin K 1 (phylloquinone) at carbon paste electrodes and its determination in plasma by adsorptive stripping voltammetry. Analyst, ,


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adsorptive stripping voltammetry on mercury film electrodes by A. Economou Download PDF EPUB FB2

Alarfaj [41] investigated the adsorptive stripping voltammetry of telmisartan with a hanging mercury drop electrode. This compound produced a catalytic hydrogen wave at − V in Britton–Robinson buffer of pHand the peak current increased with adsorptive accumulation at the electrode.

Electrochemical stripping analysis is a set of analytical chemistry methods based on voltammetry or potentiometry that are used for quantitative determination of ions in solution. Stripping voltammetry (anodic, cathodic and adsorptive) have been employed for.

Cathodic Stripping Voltammetry. Cathodic stripping voltammetry (CSV) is an analytical technique used for the analysis of low levels of analytes (principally trace metals and sulfur containing organic compounds) in aqueous solutions, and is based on the measurement of a reductive current response as a function of a potential scan toward more negative potentials.

The effect of various surfactants on the stripping response for analytes adsorbed on a mercury film electrode (MFE) was studied and compared with the effect observed under identical conditions when a hanging mercury drop electrode (HMDE) was used.

It was found that. A positive potential is applied, oxidizing the mercury electrode and forming insoluble precipitates of the anions. A negative potential then reduces (strips) the deposited film into solution.

Adsorptive stripping voltammetry - A quantitative, analytical method for trace analysis. The analyte is deposited simply by adsorption on the electrode. Adsorptive stripping voltammetry (AdSV) was successfully explored for the determination of aluminum(III) in sodium carbonate solution (1 M) on a preplated bismuth film electrode (BiFE).

Other stripping voltammetric techniques include cathodic stripping voltammetry (CSV) and adsorptive stripping voltammetry (AdSV). The basis for CSV is the oxidation of mercury followed by the formation of an insoluble film of HgL (L is the analyte) on the surface.

Determination of dinoseb by adsorptive stripping voltammetry using a mercury film electrode María Pedrero, Belén Casado, F. Javier Manuel de Villena, and Jose M. Pingarrón Fresenius' Journal of Analytical Chemistry,VolumeNumber 7, Page Cited by: Study on simultaneous measurements of trace gallium(III) and germanium(IV) by adsorptive stripping voltammetry using mercury film electrodeAuthor: Robert Piech.

A procedure for the automated on-line determination of nickel in aquatic samples was developed. It is based upon adsorptive stripping voltammetry of the dimethylglyoxime complex at a thin-mercury film electrode (TMFE) on glassy carbon substrate.

The severe problem of reproducibly renewing the TMFE was solved by the choice of an appropriate electrolyte and a special potential by: 6. STRIPPING VOLTAMMETRY 6a. ANODIC-STRIPPING ANALYSIS Principles of the method Anodic-stripping analysis is the most sensitive of all commonly used electroanalytical techniques.

Analyses can be performed at the trace level and are applicable to solutions containing metal ions in the concentration range of - M. Other advantageous features of stripping voltammetry include the. Abstract: This review describes our recent results regarding adsorptive stripping voltammetric determination of submicromolar and nanomolar concentrations of various environmentally important chemical carcinogens using both traditional (hanging mercury drop electrode, carbon paste electrode) and non-traditional types of electrodes (solid amalgam electrodes, glassy carbon paste electrodes Cited by: Abstract: The recent tendency to replace liquid mercury by less toxic electrode materials has led many analysts to investigate and design various thin film electrodes generated ex-situ or in-situ by electroplating the selected metals at different supports, and to develop new stripping and catalytic adsorptive stripping voltammetric procedures that would use them.

Catalytic adsorptive stripping voltammetry for V analysis was developed at mercury-coated gold micro-wire electrodes (MWEs, microm) in the presence of gallic acid (GA) and bromate ion. A potential of V (vs Ag/AgCl) was used to accumulate the adsorptive stripping voltammetry on mercury film electrodes book in acetate buffer (pH ) at the electrode surface followed by a differential pulse Cited by: Square wave adsorptive stripping voltammetry on mercury film electrodes Anastasios Economou, Peter R.

Fielden Analytica Chimica Acta (),   Catalytic adsorptive stripping voltammetry for V analysis was developed at mercury-coated gold micro-wire (MWE, μm) electrodes in the presence of gallic acid (GA) and bromate ion.

A potential of − V (vs Ag/AgCl) was used to accumulate the complex in acetate buffer (pH ) at the electrode surface followed by a differential pulse Cited by: Molybdenum by adsorptive catalytic stripping voltammetry 50 Figure 4. 7x10Peak current (µA)-pH curve (4x M Pb2+, 8x10 2 M KClO 3, -7 M ARS and 2x M Mo(VI) in M pH acetic acid/acetate solutions) The concentration of ARS is important for both formation of stable complex and the situation of competitive adsorption between free ARS and the ARS side of Mo(VI)-ARS by: 1.

An adsorptive stripping voltammetric method for the determination of the pesticide dinoseb (2-sec.-butyl-4,6-dinitrophenol) at the mercury film electrode is described.

The deposition of the mercury film on a glassy carbon disk electrode was optimized. The temperature, at which the mercury film was deposited, was demonstrated to have a strong influence on the stripping peaks, the first one Cited by: 5.

Voltammetric Measurements. Although early voltammetric methods used only two electrodes, a modern voltammeter makes use of a three-electrode potentiostat, such as that shown in Figure In voltammetry we apply a time-dependent potential excitation signal to the working electrode—changing its potential relative to the fixed potential of the reference electrode—and measure the current.

Thin Mercury Film Electrode. Aim To use a standard additions method to determine the levels of Copper, Lead and Cadmium in a typical tap water sample by Anodic Stripping Voltammetry (ASV) at a thin mercury film electrode.

Background Anodic Stripping Voltammetry (ASV) is a very sensitive electroanalytical techniques where aFile Size: KB. Square wave adsorptive stripping voltammetry (AdSV) in conjunction with the batch injection analysis technique has been investigated at mercury thin-film electrodes, using analysis of nickel and cobalt ions with nioxime ligand as example, and injection of sample volumes of.

This paper describes a procedure that has been optimized for the determination of lamotrigine by Differential Pulse Adsorptive Stripping Voltammetry (DPAdSV) using carbon screen-printed electrodes (CSPE) and mercury coated carbon screen-printed electrodes.

Selection of the experimental parameters was made using experimental design methodology. The detection limit found was x M and Cited by: • A thin film mercury electrode (TFME or MFE) • Can also do cathodic stripping voltammetry (CSV) or adsorptive stripping voltammetry using an anodic potential to adsorb anionic species on the surface of the electrode • Ions like MoO 4 2- Membrane covered electrodes.

Table 1 shows a summary of the optimized conditions for efavirenz determination by differential pulse adsorptive stripping voltammetry at the mercury film electrode.

Practical applications of differential pulse adsorptive stripping analysis may be affected by interferences due to the presence of metal ions and/or surface active compounds. concern, development of mercury-free electrodes for stripping voltammetry may attract interest.

Recently, a new working electrode, bismuth film plated in situ on the surface of glassy carbon disk electrode (in situ BiFE), have developed for anodic stripping voltammetric determination of copper, lead, cadmium and zinc (Wang et aI.,). An adsorptive stripping voltammetric procedure for the determina- tion of the antidepressant venlafaxine in urine using a mercury film microelectrode was developed.

The method is based on controlled adsorptive accumulation of the drug at the potential of V (vs. Ag/AgCl) in the presence of x A selection of electrodes are available depending on the application including: Gold Electrodes for the determination of mercury, and arsenic and for the use of an Hg film; HMDE Hanging mercury drop electrode with a minimum of.

This Application Bulletin describes the determination of zinc at a mercury film electrode (MFE). Zinc can also be determined simultaneously with cadmium and lead. The determination of copper at the MFE is not possible. The mercury film is plated ex-situ on a glassy carbon electrode and can be used for half a day up to one day.

Zinc can be determined at the mercury film electrode by anodic. One of these working electrodes is bismuth film electrodes (BiFEs) and has been widely explored as a replacement for the toxic hanging drop mercury electrodes and films.

In differential pulse adsorptive stripping voltammetry (DPAdSV), nanoparticles play also a very important by: 1. The shape and position of the stripping peaks in dc (linear scan) anodic stripping voltammetry at mercury thin film hydrodynamic electrodes for reversible systems are examined, focussing on rotating disc and wall-jet disc electrodes.

Stripping under forced convection is compared to non-convective stripping. cathodic stripping voltammetry is presented. The method is based on adsorptive accumulation of the complexes of Cu (II) ions with benzenesulfonyl hydrazide onto hanging mercury drop electrode (HMDE), followed by the reduction of the adsorbed species by differential pulse cathodic stripping voltammetry.

The effect of various. Cathodic stripping voltammetry (CSV) is the quantification of metals species from their reduction current. The stripping bit means that there is a preconcentration step that usually consists of adsorption of a complex with a selective ligand (usually an organic ligand) on the electrode.

Determination of iron in water samples by adsorptive stripping voltammetry with a bismuth film electrode in the presence of 1-(2-piridylazo)naphthol Rodrigo Seguraa,∗, Mar´ıa Ines Toral´ a,Veronica Arancibia´ b a Departamento de Qu´ımica Anal´ıtica, Facultad de Qu´ımica, Universidad de Chile, Las PalmerasCasilla purpose we used an electrochemical method of adsorptive stripping voltammetry (AdSV).

AdSV is the most successful method for electrochemical trace analysis with reported limits of detection down to M range.1 The sensitivity of AdSV method is based on the preconcentration, i.e., accumulation, of dissolved metal ions from.

to mv using adsorptive stripping mode. The stripping current arising was correlated with the concentration of the metal in the sample. The peak potential for mercury is detection limit of mercury by this method was ug/l.

Keywords: Adsorptive stripping voltametry, RDE, Mercury, Blood, Heavy metal, etc Introduction. Read "Adsorptive Stripping Voltammetry and/or Chronopotentiometry. Comparison and Assessment, Electroanalysis" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.

The application of a hanging mercury drop electrode, modified by adsorption of poly-L-histidine, to the determination of Cu II in aqueous solutions has been ive and rapid pre-concentration of Cu II on the poly-L-histidine film was observed, even from dilute and quiescent (II) was determined by differential-pulse adsorptive stripping voltammetry between 5 × Distinguish between (a) voltammetry and amperometry, (b) linear-scan voltammetry and pulse voltammetry.

(c) differential-pulse voltammetry and square-wave voltammetry, (d) an RDE and a ring- disk electrode,(e) faradaic impedance and double-layer capacitance, (f) a limiting current and a diffusion current, (g) laminar flow and turbulent flow, (h) the standard electrode potential and the half.

Voltammetric Measurements. Although early voltammetric methods used only two electrodes, a modern voltammeter makes use of a three-electrode potentiostat, such as that shown in Figure In voltammetry we apply a time-dependent potential excitation signal to the working electrode—changing its potential relative to the fixed potential of the reference electrode—and measure the.

A new procedure for the direct determination of picomolar levels of cobalt in seawater is presented. Cathodic stripping voltammetry is preceded by adsorptive accumulation of the cobalt−nioxime (cyclohexane-1,2-dione dioxime) complex from seawater containing 6 μM nioxime and 80 mM ammonia at pHonto a hanging mercury drop electrode, followed by reduction of the adsorbed species.

This Application Bulletin describes the determination of cadmium and lead at a mercury film electrode (MFE) by anodic stripping pdf (ASV). The mercury film is plated ex situ on a glassy carbon electrode and can be used for up to one day. With a deposition time of 30 s, the limit of detection is ß(Cd 2+) = µg/L and ß(Pb2+) = µg/L.This paper describes a procedure for the determination of antimony (III) by differential pulse anodic stripping voltammetry using a mercury film screen-printed electrode as the working electrode.

The procedure has been optimized using experimental design methodology. Under these conditions, in terms of Residual Standard Deviation (RSD), the repeatability ( %) and the reproducibility ( Cited by: ping voltammetry (ASV) and potentiometric stripping analysis (PSA).

We have chosen to re-optimise the ASV method but the same procedure may be applic-able to PSA. The conventional procedure for the determination of these heavy metals involves using either a hanging mercury drop electrode (HMDE) or a mercury film-coated electrode [1–3].